This would be an amazing feature to have to assist with fulfilment. There appears to be no easy workaround within the system to achieve this and as mentioned previously a BCC feature would be the ideal solution.

Yes I'd love to get a CC (actually BCC) copy so I know what is being purchased and what emails clients are getting. It would also be very handy for our fulfilment team to get a BCC copy automatically so they know what to send.

Automation workflows do not seem to have access to exact order contents so it can't be achieved that way, and BCCing the receipt would be easier anyway as it is an exact copy of what the client has received.

A simple field on the "Automatic Sales Receipts" page in which we can enter BCC addresses would be azaming.